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Slow dynamics and local quasi-equilibrium. Relaxation in supercooled colloidal systems

机译:慢动力学和局部准平衡。在过冷却中放松   胶体系统

摘要

We present a Fokker-Planck description of supercooled colloidal systemsexhibiting slow relaxation dynamics. By assuming the existence of a localquasi-equilibrium state during the relaxation of the system, we derive anon-Markovian Fokker-Planck equation for the non-stationary conditionalprobability. A generalized Stokes-Einstein relation containing the temperatureof the system instead of the temperature of the bath is obtained. Our resultsexplain experiments showing that the diffusion coefficient is not proportionalto the inverse of the effective viscosity at frequencies related to thediffusion time scale.
机译:我们提出了具有慢弛豫动力学的过冷胶体系统的Fokker-Planck描述。通过假设系统松弛过程中存在局部准平衡状态,我们推导了非平稳条件概率的非马尔可夫福克-普朗克方程。得到了包含系统温度而不是浴温的广义斯托克斯-爱因斯坦关系。我们的结果说明了实验,表明在与扩散时间尺度有关的频率下,扩散系数与有效粘度的倒数不成比例。

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